Institute of Physics and Materials Science, University of Natural Resources and Life Sciences, Peter Jordan Straße 82, 1190 Vienna, Austria.
Institute Applied Geology, University of Natural Resources and Life Sciences, Peter Jordan Straße 82, 1190 Vienna, Austria.
Molecules. 2020 Mar 20;25(6):1419. doi: 10.3390/molecules25061419.
Dating of clay bricks (adobe) and plasters is a relevant topic not only for building historians in the Pannonian region. Especially in vernacular architecture in this region, clay with straw amendments is a dominant construction material. The paper presents the potential of the molecular decay of these amendments to establish prediction tools for age based on infrared spectroscopic measurements. Preliminary results revealed spectral differences between the different plant parts, especially culms, nodes, and ear spindles. Based on these results, a first prediction model is presented including 14 historic samples. The coefficient of determination for the validation reached 62.2%, the (RMSE) root mean squared error amounted to 93 years. Taking the limited sample amount and the high material heterogeneity into account, this result can be seen as a promising output. Accordingly, sample size should be increased to a minimum of 100 objects and separate models for the different plant parts should be established.
对粘砖(土坯)和灰泥进行年代测定不仅是潘诺尼亚地区建筑历史学家的相关课题。在该地区的乡土建筑中,添加稻草的粘土是一种主要的建筑材料。本文提出了利用这些添加剂的分子衰变来建立基于红外光谱测量的年龄预测工具的潜力。初步结果显示,不同植物部位(特别是秸秆、节和耳轴)之间存在光谱差异。基于这些结果,提出了一个包含 14 个历史样本的初步预测模型。验证的决定系数达到 62.2%,均方根误差(RMSE)达到 93 年。考虑到样本数量有限和材料高度异质性,这一结果可以被视为一个有希望的结果。因此,应该将样本量增加到至少 100 个,并为不同的植物部位建立单独的模型。