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有机污染物吸附参数仅应在一致的线性函数系统中进行比较。

Organic contaminant sorption parameters should only be compared across a consistent system of linear functions.

作者信息

Chappell Mark A, Seiter Jennifer M, West Haley M, Miller Lesley F, Negrete Maria E, LeMonte Joshua J, Porter Beth E, Price Cynthia L, Middleton Matthew A

机构信息

U.S. Army Engineer Research & Development Center, 3909 Halls Ferry Rd, Vicksburg, MS, 39180, USA.

出版信息

Heliyon. 2020 Mar 26;6(3):e03511. doi: 10.1016/j.heliyon.2020.e03511. eCollection 2020 Mar.

DOI:10.1016/j.heliyon.2020.e03511
PMID:32258452
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7109627/
Abstract

Modeling contaminant sorption data using a linear model is very common; however, the rationale for whether the y-intercept should be constrained or not remains a subject of debate. This article justifies constraining the y-intercept in the linear model to zero. By doing so, one imposes consistency on the system of linear equations, allowing for direct comparison of the sorption coefficients.

摘要

使用线性模型对污染物吸附数据进行建模非常常见;然而,关于y轴截距是否应受约束的基本原理仍是一个有争议的话题。本文论证了将线性模型中的y轴截距约束为零的合理性。这样做,可以使线性方程组系统具有一致性,从而能够直接比较吸附系数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7321/7109627/70f22fa65de1/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7321/7109627/70f22fa65de1/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7321/7109627/70f22fa65de1/gr1.jpg

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J Environ Manage. 2016 Nov 1;182:101-110. doi: 10.1016/j.jenvman.2016.07.043. Epub 2016 Jul 22.
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Differential kinetics and temperature dependence of abiotic and biotic processes controlling the environmental fate of TNT in simulated marine systems.模拟海洋体系中控制 TNT 环境归宿的非生物和生物过程的差速动力学和温度依赖性。
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Sorption behavior of nonylphenol in terrestrial soils.
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Environ Sci Technol. 2002 Oct 1;36(19):4052-7. doi: 10.1021/es0103389.