2-[双(苄硫基)甲基]-6-甲氧基苯酚的晶体结构
Crystal structure of 2-[bis(benzylsulfanyl)methyl]-6-methoxyphenol.
作者信息
Raghuvanshi Abhinav, Knauer Lena, Viau Lydie, Knorr Michael, Strohmann Carsten
机构信息
Institut UTINAM UMR 6213 CNRS, Université Bourgogne Franche-Comté, 16, Route de Gray, 25030 Besançon Cedex, France.
Anorganische Chemie, TU Dortmund University, Otto-Hahn-Str. 6/6a, D-44227 Dortmund, Germany.
出版信息
Acta Crystallogr E Crystallogr Commun. 2020 Mar 3;76(Pt 4):484-487. doi: 10.1107/S2056989020002091. eCollection 2020 Apr 1.
The title compound, CHOS, , represents an example of an -vanillin-based functionalized di-thio-ether, which could be useful as a potential chelating ligand or bridging ligand for coordination chemistry. This di-thio-acetal crystallizes in the ortho-rhom-bic space group . The phenyl rings of the benzyl groups and that of the vanillin unit form dihedral angles of 35.38 (6) and 79.77 (6)°, respectively. The crystal structure, recorded at 100 K, displays both weak intra-molecular O-H⋯O and inter-molecular O-H⋯S hydrogen bonding.
标题化合物CHOS……代表了一种基于香草醛的官能化二硫醚，它可能作为配位化学中潜在的螯合配体或桥联配体。这种二硫缩醛结晶于正交晶系空间群……。苄基的苯环与香草醛单元的苯环分别形成35.38（6）°和79.77（6）°的二面角。在100K记录的晶体结构显示出分子内弱的O-H⋯O和分子间O-H⋯S氢键。 （注：原文中“CHOS,”后面省略号部分内容缺失，翻译时按原文呈现）
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