Szynkiewicz Natalia, Chojnacki Jarosław, Grubba Rafał
Department of Inorganic Chemistry, Faculty of Chemistry, Gdańsk University of Technology, 11/12 Gabriela Narutowicza Strasse, 80-233 Gdańsk, Poland.
Inorg Chem. 2020 May 4;59(9):6332-6337. doi: 10.1021/acs.inorgchem.0c00435. Epub 2020 Apr 14.
Herein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with NO via insertion of a single oxygen atom into the P-B bond and formation of a P-O-B bond system. Borylphosphine and borylphosphinite capture SO and activate it in an irreversible and reversible manner, respectively.
在此，我们展示了首次使用一氧化二氮将硼基膦转化为硼基亚膦酸酯。硼基膦通过单个氧原子插入P-B键并形成P-O-B键体系与NO发生反应。硼基膦和硼基亚膦酸酯分别以不可逆和可逆的方式捕获SO并使其活化。
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