磷化物对一氧化二氮的共价捕获。
Covalent capture of nitrous oxide by phosphanides.
作者信息
Genoux Alexandre, Wong Tak Hin, Fadaei-Tirani Farzaneh, Severin Kay
机构信息
Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland.
出版信息
Chem Commun (Camb). 2025 Sep 12. doi: 10.1039/d5cc04154f.
Abstract
Potassium phosphanides with adamantyl or -butyl groups form covalent adducts with NO. The adducts are sufficiently stable to permit crystallographic analyses and reactivity studies.
摘要
含有金刚烷基或叔丁基的磷化物与一氧化氮形成共价加合物。这些加合物足够稳定，可用于晶体学分析和反应性研究。
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