Uribe Lina, Giraldo Juan D, Vargas Alejandro
Escuela de Ingeniería Civil de Minas, Universidad de Talca, Talca 3460000, Chile.
Materials (Basel). 2020 Apr 11;13(8):1806. doi: 10.3390/ma13081806.
Ceramic foams were fabricated without using melting pots through the direct foaming of compacted powder mixtures of commercial quartz (SiO) with fluxing agents (NaCO and CaO) and a foaming agent (NaSiO·5HO) at a relatively low temperature range (850-870 °C). The effects of the pressing pressure of the powders, the foaming time, foaming temperature, and mixture content were evaluated. The obtained cellular solid materials presented an acceptable volumetric expansion at a pressing pressure of 4 t. The materials only presented porosity at a minimum temperature of 850 °C and at a minimum time of 30 min. All the foamed samples showed an acceptable symmetric expansion and non-appreciable fissures. The study of the mixture content through the statistical software MODDE® shows that the porosity of the samples was principally affected by the NaSiO content and the foaming temperature. The samples obtained at the optimum controlling factors proposed by this statistical software presented an apparent density, porosity, and mechanical strength of 1.09 ± 0.03 g/cm, 56.01% ± 1.12%, and 3.90 ± 0.16 MPa, respectively. Glass and ceramics foams such as those obtained in this work become attractive as insulation materials in applications where high temperatures occur due to their higher melting points.
通过在相对较低的温度范围(850 - 870°C)下,将商用石英(SiO)与助熔剂(Na₂CO₃和CaO)以及发泡剂(Na₂SiO₃·5H₂O)的压实粉末混合物直接发泡,制备了陶瓷泡沫,且未使用熔炉。评估了粉末的压制压力、发泡时间、发泡温度和混合物含量的影响。在4吨的压制压力下,所获得的多孔固体材料呈现出可接受的体积膨胀。这些材料仅在最低温度850°C和最短时间30分钟时出现孔隙率。所有发泡样品均显示出可接受的对称膨胀且无明显裂缝。通过统计软件MODDE®对混合物含量的研究表明,样品的孔隙率主要受Na₂SiO₃含量和发泡温度的影响。在该统计软件提出的最佳控制因素下获得的样品,其表观密度、孔隙率和机械强度分别为1.09±0.03 g/cm³、56.01%±1.12%和3.90±0.16 MPa。像本工作中所获得的玻璃和陶瓷泡沫,由于其较高的熔点,在高温应用中作为隔热材料变得很有吸引力。