Tunable Metal Oxide Shell as a Spacer to Study Energy Transfer in Semiconductor Nanocrystals.

Colloidal semiconductor nanocrystals (NCs) are promising components in various optoelectronic and photocatalytic devices; however, the mechanism of energy transport in these materials remains to be further understood. Here, we investigate the distance dependence of the electronic interactions between CsPbBr nanocubes and CdSe nanoplateles using an alumina (AlO) shell as a spacer. CsPbBr@AlO core@shell NCs are synthesized via colloidal atomic layer deposition (c-ALD), which allows us to fine-tune the oxide thickness and thus the distance between the two NCs. This versatile material platform shows that the electronic interactions between the CsPbBr NCs and the CdSe nanoplatelets can be tuned from electron to energy transfer by increasing the shell thickness, whereas previous studies on the same system had been limited to the former. Considering the applicability of the c-ALD to different NCs, we suggest that metal oxide shell spacers synthesized by this approach can generally be used to study energy-transfer mechanisms at the nanoscale.