A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991 Moscow, Russia.
Institut Charles Gerhardt Montpellier UMR 5253, Univ. Montpellier, CNRS, ENSCM, 8 rue de l'Ecole Normale, Montpellier 34296 Cedex 5, France and Institut Universitaire de France, IUF, 1 rue Descartes, 75231 Paris Cedex 5, France.
Org Biomol Chem. 2020 May 6;18(17):3274-3280. doi: 10.1039/d0ob00580k.
An efficient synthetic approach to novel α-CF3-substituted E-dehydroornithine derivatives and their phosphorus analogues has been developed via the Cu(i)-catalyzed hydroamination of trifluoromethyl-containing α-allenyl-α-aminocarboxylates and α-allenyl-α-aminophosphonates with primary and secondary amines.
已开发出一种通过含三氟甲基的α-烯丙基-α-氨甲酰基酯和α-烯丙基-α-氨膦酸酯与伯胺和仲胺的 Cu(i)催化的氨氢化反应，来合成新型α-CF3 取代 E-去鸟氨酸衍生物及其磷类似物的有效方法。
