通过铜（I）催化的氟化烯炔串联胺化/环化反应合成功能化氮杂环庚三烯
Synthesis of Functionalized Azepines via Cu(I)-Catalyzed Tandem Amination/Cyclization Reaction of Fluorinated Allenynes.
作者信息
Philippova Anna N, Vorobyeva Daria V, Gribanov Pavel S, Godovikov Ivan A, Osipov Sergey N
机构信息
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova str., Moscow 119991, Russia.
出版信息
Molecules. 2022 Aug 15;27(16):5195. doi: 10.3390/molecules27165195.
Abstract
An efficient method for the selective preparation of trifluoromethyl-substituted azepin-2-carboxylates and their phosphorous analogues has been developed via Cu(I)-catalyzed tandem amination/cyclization reaction of functionalized allenynes with primary and secondary amines.
摘要
通过铜（I）催化功能化联烯炔与伯胺和仲胺的串联胺化/环化反应，开发了一种选择性制备三氟甲基取代的氮杂环庚烷-2-羧酸酯及其磷类似物的有效方法。
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