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一锅微波辅助植物还原法制备 FeO/Ag 纳米复合材料:作为阳光驱动光催化剂、抗菌和抗癌剂的潜在应用。

Facile one pot microwave-assisted green synthesis of FeO/Ag nanocomposites by phytoreduction: Potential application as sunlight-driven photocatalyst, antibacterial and anticancer agent.

机构信息

Department of Chemistry, PGP College of Arts and science, Namakkal 637 207, Tamil Nadu, India.

Department of Physics, Faculty of Applied Science, Umm Al-Qura University, PO.Box 21955, Makkah, Saudi Arabia.

出版信息

J Photochem Photobiol B. 2020 Jun;207:111885. doi: 10.1016/j.jphotobiol.2020.111885. Epub 2020 Apr 24.

Abstract

Herein, we report a one-pot microwave assisted method to prepare an efficient FeO/Ag nanocomposites (NCs) using Aloe vera (A. vera) gel extract as a mild, safe, renewable and active stabilizer without any harmful reagent. The advanced characterization techniques including XRD, FT-IR, UV-DRS, PL, TGA, SEM-EDX, TEM, DLS, Elemental mapping, VSM and BET were applied to analyze the morphology and structure of the prepared FeO/Ag NCs. The results exhibited that the FeO/Ag NCs was successfully synthesized by greener route. Furthermore, these bio-reduced FeO/Ag NCs was tested for its catalytic degradation toward methylene blue (MB) as a model contaminant and exhibited outstanding photocatalytic degradation efficiency with 88.2% removal rate in 140 min. It was worth pointing out that the FeO/Ag nanoparticles facilitated the charge transportation and inhibit the charge recombination of an electron in the conduction band. Additionally, the prepared FeO/Ag NCs was studied for their in-vitro antibacterial activity against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) bacteria and anticancer properties against A549 cell lines (human lung cancer). The biological results of this study demonstrated that A. vera gel extract derived FeO/Ag NCs showed significant inhibition properties against bacterial strains and also capable of achieving superior action against A549 cancer cell lines.

摘要

在此,我们报告了一种使用芦荟凝胶提取物作为温和、安全、可再生和活性稳定剂的一锅微波辅助方法来制备高效的 FeO/Ag 纳米复合材料 (NCs),而无需任何有害试剂。先进的表征技术,包括 XRD、FT-IR、UV-DRS、PL、TGA、SEM-EDX、TEM、DLS、元素映射、VSM 和 BET,用于分析制备的 FeO/Ag NCs 的形态和结构。结果表明,通过更环保的路线成功合成了 FeO/Ag NCs。此外,这些生物还原的 FeO/Ag NCs 被测试了其对亚甲基蓝 (MB) 作为模型污染物的催化降解性能,并表现出出色的光催化降解效率,在 140 分钟内去除率达到 88.2%。值得指出的是,FeO/Ag 纳米颗粒促进了电荷的传输并抑制了导带中电子的复合。此外,还研究了制备的 FeO/Ag NCs 对金黄色葡萄球菌 (S. aureus) 和大肠杆菌 (E. coli) 细菌的体外抗菌活性以及对 A549 细胞系(人肺癌)的抗癌特性。这项研究的生物学结果表明,芦荟凝胶提取物衍生的 FeO/Ag NCs 对细菌菌株表现出显著的抑制特性,并且对 A549 癌细胞系也具有优异的作用。

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