Wang Jingfeng, Liu Yuyan, Cheng Zhongjun, Xie Zhimin, Yin Liang, Wang Wu, Song Yingbin, Zhang Haiyang, Wang Youshan, Fan Zhimin
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, P. R. China.
National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin, 150080, P. R. China.
Angew Chem Int Ed Engl. 2020 Aug 10;59(33):14029-14033. doi: 10.1002/anie.202003737. Epub 2020 Jun 4.
MXene (Ti C T ) is a new 2D material with both hydrophilicity and high electrical conductivity, and it has shown promise in smart electronic devices. Reported herein is a homogeneous MXene film actuator with high electrical conductivity triggered by moisture gradients. The actuator is highly sensitive to moisture and undergoes deformation, with the maximum bending angle as high as 155° at a relative humidity difference of 65 %. Several analysis methods show that the humidity drive and large deformation of the MXene film occur in situ by asymmetric expansion of the bilayer structure. The combination of deformation and electrical conductivity makes this film applicable to flexible excavators, electrical switches, and other fields, applications that are difficult to achieve directly by using other 2D materials. More importantly, this work further expands the new application range of MXene materials and provides new opportunities for building the next generation of high-conductivity smart actuators.
MXene(Ti₃C₂Tₓ)是一种兼具亲水性和高导电性的新型二维材料,在智能电子设备中展现出了应用前景。本文报道了一种由湿度梯度触发的具有高导电性的均匀MXene薄膜致动器。该致动器对湿度高度敏感并会发生变形,在相对湿度差为65%时,最大弯曲角度高达155°。多种分析方法表明,MXene薄膜的湿度驱动和大变形是通过双层结构的不对称膨胀原位发生的。变形与导电性的结合使得这种薄膜适用于柔性挖掘机、电气开关等领域,而这些应用是直接使用其他二维材料难以实现的。更重要的是,这项工作进一步拓展了MXene材料的新应用范围,并为构建下一代高导电性智能致动器提供了新机遇。