School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, 1 Gwanak-ro, Gwanak-Gu, Seoul 08826, Republic of Korea.
School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, Republic of Korea.
Bioresour Technol. 2020 Aug;310:123473. doi: 10.1016/j.biortech.2020.123473. Epub 2020 May 4.
The global economy is threatened by the depletion of fossil resources and fluctuations in fossil fuel prices, and thus it is necessary to exploit sustainable energy sources. Carbon-neutral fuels including bio-oil obtained from biomass pyrolysis can act as alternatives to fossil fuels. Co-pyrolysis of lignocellulosic biomass and plastic is efficient to upgrade the quality of bio-oil because plastic facilitates deoxygenation. However, catalysts are required to produce bio-oil that is suitable for potential use as transportation fuel. This review presents an overview of recent advances in catalytic co-pyrolysis of biomass and plastic from the perspective of chemistry, catalyst, and feedstock pretreatment. Additionally, this review introduces not only recent research results of acid catalysts for catalytic co-pyrolysis, but also recent approaches that utilize base catalysts. Future research directions are suggested for commercially feasible co-pyrolysis process.
全球经济受到化石资源枯竭和化石燃料价格波动的威胁,因此有必要开发可持续能源。包括生物油在内的碳中和燃料可以作为化石燃料的替代品,生物油是通过生物质热解获得的。木质纤维素生物质和塑料的共热解可以有效地提高生物油的质量,因为塑料有助于脱氧。然而,需要催化剂来生产适合作为运输燃料的生物油。本综述从化学、催化剂和原料预处理的角度介绍了生物质和塑料共热解的最新进展。此外,本综述不仅介绍了用于催化共热解的酸催化剂的最新研究成果,还介绍了利用碱催化剂的最新方法。为了实现商业可行的共热解过程,提出了未来的研究方向。