Kuang Wandi, Meng Xiangjian, Wang Caihong, Talluri Bhusankar, Thomas Tiju, Jiang Chunjie, Liu Siqi, Yang Minghui
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, P. R. China.
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.
ACS Omega. 2020 Apr 22;5(17):9969-9976. doi: 10.1021/acsomega.0c00288. eCollection 2020 May 5.
Nitridation of CoWO/CdS nanocomposite results in the formation of metal nitrides on the surface of CdS. The high electrical conductivity, appropriate binding energy for hydrogen, and Pt-like properties of the surface nitrides promote the H evolution performance. Therefore, the optimal performance of nitrided CoWO/CdS (CoWO/CdS-N, 3650 μmol·h·g) is higher than that of Pt/CdS (2948 μmol·h·g).
CoWO/CdS纳米复合材料的氮化作用导致在CdS表面形成金属氮化物。表面氮化物的高电导率、合适的氢结合能以及类铂性质促进了析氢性能。因此,氮化CoWO/CdS(CoWO/CdS-N,3650 μmol·h·g)的最佳性能高于Pt/CdS(2948 μmol·h·g)。