Kim Young-Kyun, Yang Sangsun, Lee Kee-Ahn
Department of Materials Science and Engineering, Inha University, Incheon, 22212, Republic of Korea.
Korea Institute of Materials Science (KIMS), Changwon, 51508, Republic of Korea.
Sci Rep. 2020 May 15;10(1):8045. doi: 10.1038/s41598-020-65073-2.
The microstructure, temperature-dependent mechanical properties and deformation behaviors of equiatomic CoCrFeMnNi high-entropy alloy (HEA) additively manufactured by selective laser melting (SLM) were investigated. SLM-built HEA had a face-centered cubic (FCC) single-phase random solid solution. In addition, SLM-built HEA was composed of epitaxial growth grains, dislocation network and nano-sized oxides. Room- and high-temperature compression tests confirmed that SLM-built HEA has outstanding mechanical properties in all temperature ranges compared to equiatomic CoCrFeMnNi HEAs reported up to the present. The excellent mechanical properties of SLM-built HEA were achieved with fine grains, high dislocation density and fine precipitates at low temperatures (25 °C to 600 °C), and by high dislocation density and fine precipitates at high temperatures (700 °C or higher). On the other hand, the deformation microstructure showed that slip and deformation twins are the main deformation mechanisms from 25 °C to 600 °C, and slip and partial recrystallization are the main deformation mechanisms above 700 °C. Based on the above findings, this study also discusses correlations among the microstructure, superior mechanical properties and deformation mechanisms of SLM-built equiatomic CoCrFeMnNi HEA.
研究了通过选择性激光熔化(SLM)增材制造的等原子CoCrFeMnNi高熵合金(HEA)的微观结构、温度依赖性力学性能和变形行为。SLM制造的HEA具有面心立方(FCC)单相随机固溶体。此外,SLM制造的HEA由外延生长晶粒、位错网络和纳米级氧化物组成。室温及高温压缩试验证实,与目前报道的等原子CoCrFeMnNi HEA相比,SLM制造的HEA在所有温度范围内均具有出色的力学性能。SLM制造的HEA的优异力学性能是通过低温(25°C至600°C)下的细晶粒、高位错密度和细小析出相,以及高温(700°C或更高)下的高位错密度和细小析出相实现的。另一方面,变形微观结构表明,从25°C到600°C,滑移和变形孪晶是主要变形机制,而在700°C以上,滑移和部分再结晶是主要变形机制。基于上述发现,本研究还讨论了SLM制造的等原子CoCrFeMnNi HEA的微观结构、优异力学性能和变形机制之间的相关性。