镍催化的氢转移策略：腈与醇的化学选择性烷基化反应
Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols.
作者信息
Bera Sourajit, Bera Atanu, Banerjee Debasis
机构信息
Department of Chemistry, Laboratory of Catalysis and Organic Synthesis, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand, India.
出版信息
Chem Commun (Camb). 2020 Jun 23;56(50):6850-6853. doi: 10.1039/d0cc02261f.
PMID:32432612
Abstract
The first nickel-catalyzed hydrogen-borrowing alkylation of a series of aryl acetonitriles with a variety of aryl, heteroaryl, allylic and alkyl alcohols releasing water as the by-product (>33 examples, up to 90% yield) is reported.
摘要
报道了首例镍催化一系列芳基乙腈与多种芳基、杂芳基、烯丙基和烷基醇的借氢烷基化反应，该反应以水作为副产物（>33个例子，产率高达90%）。
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