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磺胺甲噁唑药物在不同 pH 值下对碳纳米管改性衍生物的吸附。

Adsorption of Sulfamethazine Drug onto the Modified Derivatives of Carbon Nanotubes at Different pH.

机构信息

Department of General and Physical Chemistry, Faculty of Sciences, University of Pécs, Ifjúság 6, H-7624 Pécs, Hungary.

Institute of Organic and Medicinal Chemistry, Medical School, University of Pécs, Szigeti 12, H-7624 Pécs, Hungary.

出版信息

Molecules. 2020 May 27;25(11):2489. doi: 10.3390/molecules25112489.

DOI:10.3390/molecules25112489
PMID:32471230
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7321183/
Abstract

The sulfamethazine drug interaction with carbon nanotubes was investigated with the aim of improving the adsorption capacity of the adsorptive materials. Experiments were performed to clarify how the molecular environment affects the adsorption process. Single-walled carbon nanotubes have a higher removal efficiency of sulfamethazine than pristine or functionalized multi-walled carbon nanotubes. Although the presence of cyclodextrin molecules improves the solubility of sulfamethazine, it reduces the adsorption capacity of the carbon nanotube towards the sulfamethazine drug and, therefore, inhibits the removal of these antibiotic pollutants from waters by carbon nanotubes.

摘要

研究了磺胺甲噁唑与碳纳米管的相互作用,旨在提高吸附材料的吸附容量。实验旨在阐明分子环境如何影响吸附过程。与原始或功能化多壁碳纳米管相比,单壁碳纳米管对磺胺甲噁唑的去除效率更高。尽管环糊精分子的存在提高了磺胺甲噁唑的溶解度,但它降低了碳纳米管对磺胺甲噁唑药物的吸附能力,从而抑制了碳纳米管从水中去除这些抗生素污染物。

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Thermodynamic Characterization of the Interaction between the Antimicrobial Drug Sulfamethazine and Two Selected Cyclodextrins.磺胺甲噁唑与两种选定环糊精相互作用的热力学特征。
Molecules. 2019 Dec 13;24(24):4565. doi: 10.3390/molecules24244565.
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采用天然和随机甲基化的β-环糊精对磺胺甲噁唑进行包合:客体偶极性质的作用。
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