Singh Simrjit, Faraz Mohd, Khare Neeraj
Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016, India.
Department of Electrical and Systems Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
ACS Omega. 2020 May 21;5(21):11874-11882. doi: 10.1021/acsomega.9b03913. eCollection 2020 Jun 2.
Semiconductor heterostructures have attracted intensive research attention during the past few years owing to their great potential for energy and environmental remediation related applications. Effective optical absorption and efficient separation of photogenerated charge carriers are among the key factors for achieving high efficiency in a photocatalytic process. This mini-review summarizes state-of-the-art activities in designing nanosemiconductor heterostructures using multifunctional semiconductors for solar-to-hydrogen conversion and degradation of organic pollutants. Various novel design strategies such as semiconductor/graphene heterojunctions including graphene as a semimetal and photosensitizer, semiconductor/ferromagnetic, and semiconductor/ferroelectric nanoheterostructures for enhancing the performance of photocatalytic processes have been discussed. Finally, key challenges and future prospects for designing more efficient photocatalytic materials are briefly outlined.
在过去几年中,半导体异质结构因其在能源和环境修复相关应用方面的巨大潜力而受到了广泛的研究关注。有效的光吸收和光生载流子的高效分离是在光催化过程中实现高效率的关键因素之一。本综述总结了利用多功能半导体设计纳米半导体异质结构用于太阳能制氢和有机污染物降解的最新研究进展。讨论了各种新颖的设计策略,如以石墨烯作为半金属和光敏剂的半导体/石墨烯异质结、半导体/铁磁体以及半导体/铁电体纳米异质结构,以提高光催化过程的性能。最后,简要概述了设计更高效光催化材料的关键挑战和未来前景。