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用于室温下氨气检测的具有增强传感性能的SnO@PANI纳米管的界面设计

Interface Design of SnO@PANI Nanotube With Enhanced Sensing Performance for Ammonia Detection at Room Temperature.

作者信息

Jia Anqiang, Liu Bitao, Liu Haiyan, Li Qiufeng, Yun Yingxia

机构信息

Department of Urban and Rural Planning, School of Architecture, Tianjin University, Tianjin, China.

Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing, China.

出版信息

Front Chem. 2020 Jun 3;8:383. doi: 10.3389/fchem.2020.00383. eCollection 2020.

Abstract

Gas sensors with excellent stability and a high response at room temperature has drawn a great deal of attention and demand for them is huge. Surface designs provide inspiration toward making more useful sensor devices. The facile electrospinning process and Ar plasma treatment are used to fabricate rich and stable oxygen vacancies that contain a core-shell structured SnO polyaniline (PANI) nanotube. It shows that the induced surface oxygen vacancies would accelerate the PANI shell to generate more protons, which can enhance its sensor responsibility through reacting with the target Ammonia (NH) gas. It was also found that the obtained oxygen vacancies can be well-protected by the coated PANI shell, which enhance and stabilize the gas response. It shows that the room temperature for the gas response of NH can reach up to 35.3 at 100 ppm. Finally, its good stability is demonstrated by the response-recovery performances carried out over 3 months and multiple cycles. This work indicates that this well-designed PANI-coated plasma-treated SnO is a potential way to design ammonia gas sensors.

摘要

具有出色稳定性且在室温下具有高响应性的气体传感器引起了广泛关注,对其需求巨大。表面设计为制造更实用的传感器设备提供了灵感。采用简便的静电纺丝工艺和氩等离子体处理来制造富含且稳定的氧空位,形成核壳结构的SnO聚苯胺(PANI)纳米管。结果表明,诱导产生的表面氧空位会促使PANI壳层产生更多质子,通过与目标氨气(NH₃)气体反应可增强其传感器响应性能。还发现所获得的氧空位能够被包覆的PANI壳层很好地保护,从而增强并稳定气体响应。结果表明,在100 ppm时,NH₃气体响应的室温可达35.3。最后,通过3个月以上的响应 - 恢复性能测试和多次循环展示了其良好的稳定性。这项工作表明,这种精心设计的聚苯胺包覆的等离子体处理的SnO是设计氨气传感器的一种潜在方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b7d/7283607/a6b32e25ea0b/fchem-08-00383-g0001.jpg

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