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伊通河城区段沉积物中重金属的形态分布及风险评价

[Speciation Distribution and Risk Assessment of Heavy Metals in Sediments from the Yitong River City Area].

作者信息

Jiang Shi-Xin, Zhai Fu-Jie, Zhang Chao, Wang Meng-Meng, Shan Bao-Qing

机构信息

College of Energy and Environmental Engineering, Hebei University of Engineering, Handan 056038, China.

State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environment Sciences, Chinese Academy of Sciences, Beijing 100085, China.

出版信息

Huan Jing Ke Xue. 2020 Jun 8;41(6):2653-2663. doi: 10.13227/j.hjkx.201910113.

Abstract

The total content and chemical speciation of Cd, Cr, Cu, Ni, Pb, and Zn in seven short cores sampled from the Yitong River from Changchun City were analyzed to assess the pollution levels and potential ecological risks of heavy metals in the sediments. The results demonstrated that the total contents of Cd, Cr, Cu, Ni, Pb, and Zn in sediments were 0.10-1.18, 23.57-66.35, 11.27-43.95, 10.78-29.82, 15.02-60.81, and 54.27-175.83 mg·kg, respectively. The acid-soluble fraction of Cd varied from 42.1% to 51.28%, whereas Cr, Ni, and Zn were mainly found in the residual fraction; their mass fractions were 63.54%-79.91%, 35.16%-53.75%, and 27.55%-57.55%, respectively. The vertical results of pollution degree and ecological risk assessment indicated that the studied sediment was polluted by Cd, Cu, Pb, and Zn, and the ecological risk of Cd was the highest, followed by Zn and Cu. Each group of metals in each core showed a similar vertical variation, and the ecological risk of metals in sediment of 4-8 cm depth was relatively high. Cd, Zn, and Pb in the sediments of Yitong River were mainly from industrial pollution and municipal sewage discharge, and Cu could be attributed to both natural processes and human activities, whereas Cr and Ni may be attributed to natural processes.

摘要

分析了采自长春市伊通河的7个短柱状沉积物岩芯中镉(Cd)、铬(Cr)、铜(Cu)、镍(Ni)、铅(Pb)和锌(Zn)的总量及化学形态,以评估沉积物中重金属的污染水平和潜在生态风险。结果表明,沉积物中Cd、Cr、Cu、Ni、Pb和Zn的总量分别为0.10 - 1.18、23.57 - 66.35、11.27 - 43.95、10.78 - 29.82、15.02 - 60.81和54.27 - 175.83 mg·kg。Cd的酸溶态含量在42.1%至51.28%之间变化,而Cr、Ni和Zn主要以残渣态存在,其质量分数分别为63.54% - 79.91%、35.16% - 53.75%和27.55% - 57.55%。污染程度和生态风险评估的垂向结果表明,研究区域沉积物受到Cd、Cu、Pb和Zn污染,其中Cd的生态风险最高,其次是Zn和Cu。各岩芯中每组金属均呈现相似的垂向变化,4 - 8 cm深度沉积物中金属的生态风险相对较高。伊通河沉积物中的Cd、Zn和Pb主要来源于工业污染和城市污水排放,Cu可能归因于自然过程和人类活动,而Cr和Ni可能归因于自然过程。

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