Key Laboratory of Applied Surface and Colloid Chemistry of MOE, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China.
Chem Commun (Camb). 2020 Jul 14;56(56):7809-7812. doi: 10.1039/d0cc00952k.
Rh(iii)-catalyzed synthesis of vicinal diamides has been realized via elaboration of an authenticated Rh-C(sp3) species generated via initial intramolecular amidorhodation of olefins. The second amidation was achieved using both electrophilic and nucleophilic amidating reagents. The reactions proceeded under mild conditions with good yield, broad substrate scope, and excellent functional-group tolerance.
铑(III)催化的邻二酰胺合成是通过详细研究初始烯烃分子内酰胺化生成的经证实的铑-C(sp3)物种来实现的。第二个酰胺化反应使用亲电和亲核酰胺化试剂来完成。反应在温和的条件下进行，具有良好的收率、广泛的底物范围和优异的官能团耐受性。
