一种双功能配体可使金催化的末端炔烃在温和反应条件下进行氢芳基化反应。
A Bifunctional Ligand Enables Gold-Catalyzed Hydroarylation of Terminal Alkynes under Soft Reaction Conditions.
作者信息
Li Ting, Yang Yuhan, Luo Baomin, Li Bo, Zong Luyi, Kong Weiguang, Yang Hao, Cheng Xinpeng, Zhang Liming
机构信息
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, P. R. China.
Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States.
出版信息
Org Lett. 2020 Aug 7;22(15):6045-6049. doi: 10.1021/acs.orglett.0c02130. Epub 2020 Jul 9.
PMID:32643944
Abstract
An efficient gold-catalyzed hydroarylation of alkynes under soft reaction conditions is developed by utilizing a bifunctional ligand. This transformation features a broad substrate scope and thus exhibits moderate to excellent efficiency.
摘要
通过使用双功能配体，开发了一种在温和反应条件下高效的金催化炔烃氢芳基化反应。该转化具有广泛的底物范围，因此表现出中等至优异的效率。
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