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用于有机合成的可见光介导的铜光催化

Visible-light-mediated copper photocatalysis for organic syntheses.

作者信息

Zhang Yajing, Wang Qian, Yan Zongsheng, Ma Donglai, Zheng Yuguang

机构信息

Traditional Chinese Medicine Processing Technology Innovation Center of Hebei Province, Hebei University of Chinese Medicine, Shijiazhuang, 050200, P. R. China.

出版信息

Beilstein J Org Chem. 2021 Oct 12;17:2520-2542. doi: 10.3762/bjoc.17.169. eCollection 2021.

DOI:10.3762/bjoc.17.169
PMID:34760022
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8551910/
Abstract

Photoredox catalysis has been applied to renewable energy and green chemistry for many years. Ruthenium and iridium, which can be used as photoredox catalysts, are expensive and scarce in nature. Thus, the further development of catalysts based on these transition metals is discouraged. Alternative photocatalysts based on copper complexes are widely investigated, because they are abundant and less expensive. This review discusses the scope and application of photoinduced copper-based catalysis along with recent progress in this field. The special features and mechanisms of copper photocatalysis and highlights of the applications of the copper complexes to photocatalysis are reported. Copper-photocatalyzed reactions, including alkene and alkyne functionalization, organic halide functionalization, and alkyl C-H functionalization that have been reported over the past 5 years, are included.

摘要

光氧化还原催化已应用于可再生能源和绿色化学领域多年。钌和铱可用作光氧化还原催化剂，但它们价格昂贵且在自然界中稀缺。因此，基于这些过渡金属的催化剂的进一步发展受到阻碍。基于铜配合物的替代光催化剂受到广泛研究，因为它们储量丰富且成本较低。本文综述了光诱导铜基催化的范围和应用以及该领域的最新进展。报道了铜光催化的特殊性质和机理以及铜配合物在光催化中的应用亮点。还包括过去5年报道的铜光催化反应，如烯烃和炔烃官能化、有机卤化物官能化以及烷基C-H官能化。

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