• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

碳纳米管刺激二烷基二硫代磷酸锌抗磨膜形成的间接摩擦学作用

The Indirect Tribological Role of Carbon Nanotubes Stimulating Zinc Dithiophosphate Anti-Wear Film Formation.

作者信息

Kałużny Jarosław, Kulczycki Andrzej, Dzięgielewski Wojciech, Piasecki Adam, Gapiński Bartosz, Mendak Michał, Runka Tomasz, Łukawski Damian, Stepanenko Oleksandr, Merkisz Jerzy, Kempa Krzysztof

机构信息

Faculty of Civil and Transport Engineering, Poznan University of Technology, 60-965 Poznań, Poland.

Air Force Institute of Technology, 01-494 Warsaw, Poland.

出版信息

Nanomaterials (Basel). 2020 Jul 8;10(7):1330. doi: 10.3390/nano10071330.

DOI:10.3390/nano10071330
PMID:32650442
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7408134/
Abstract

Experimental studies reveal that the simultaneous addition of zinc dialkyl dithiophosphates (ZDDPs) and multi-wall carbon nanotubes (MWCNTs) to a poly-alpha-olefin base oil strongly reduces wear. In this paper, it is shown that MWCNTs promote the formation of an anti-wear (AW) layer on the metal surface that is much thicker than what ZDDPs can create as a sole additive. More importantly, the nanotubes' action is indirect, i.e., MWCNTs neither mechanically nor structurally strengthen the AW film. A new mechanism for this effect is also proposed, which is supported by detailed tribometer results, friction track 3D-topography measurements, electron diffraction spectroscopy (EDS), and Raman spectroscopy. In this mechanism, MWCNTs mediate the transfer of both thermal and electric energy released on the metal surface in the friction process. As a result, this energy penetrates more deeply into the oil volume, thus extending the spatial range of tribochemical reactions involving ZDDPs.

摘要

实验研究表明，将二烷基二硫代磷酸锌（ZDDPs）和多壁碳纳米管（MWCNTs）同时添加到聚α-烯烃基础油中可显著降低磨损。本文表明，MWCNTs促进了金属表面抗磨（AW）层的形成，该抗磨层比ZDDPs作为单一添加剂时所形成的抗磨层要厚得多。更重要的是，纳米管的作用是间接的，即MWCNTs既不会在机械上也不会在结构上强化抗磨膜。本文还提出了一种对此效应的新机制，详细的摩擦磨损试验机结果、摩擦轨迹三维形貌测量、电子衍射光谱（EDS）和拉曼光谱都支持这一机制。在该机制中，MWCNTs介导了摩擦过程中金属表面释放的热能和电能的传递。结果，这种能量更深入地渗透到油相中，从而扩展了涉及ZDDPs的摩擦化学反应的空间范围。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/4afad9c500e7/nanomaterials-10-01330-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/470b62285625/nanomaterials-10-01330-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/03073a8a968f/nanomaterials-10-01330-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/229932dc6384/nanomaterials-10-01330-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/fe241e18be25/nanomaterials-10-01330-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/2a4f54a15374/nanomaterials-10-01330-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/04f67654ced0/nanomaterials-10-01330-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/295c5d9d9671/nanomaterials-10-01330-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/e471b3521c03/nanomaterials-10-01330-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/4afad9c500e7/nanomaterials-10-01330-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/470b62285625/nanomaterials-10-01330-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/03073a8a968f/nanomaterials-10-01330-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/229932dc6384/nanomaterials-10-01330-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/fe241e18be25/nanomaterials-10-01330-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/2a4f54a15374/nanomaterials-10-01330-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/04f67654ced0/nanomaterials-10-01330-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/295c5d9d9671/nanomaterials-10-01330-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/e471b3521c03/nanomaterials-10-01330-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0150/7408134/4afad9c500e7/nanomaterials-10-01330-g009.jpg

相似文献

1
The Indirect Tribological Role of Carbon Nanotubes Stimulating Zinc Dithiophosphate Anti-Wear Film Formation.碳纳米管刺激二烷基二硫代磷酸锌抗磨膜形成的间接摩擦学作用
Nanomaterials (Basel). 2020 Jul 8;10(7):1330. doi: 10.3390/nano10071330.
2
Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties.多壁碳纳米管增强聚甲基丙烯酸甲酯纳米复合材料：其摩擦与磨损性能的实验研究
Polymers (Basel). 2023 Jun 22;15(13):2785. doi: 10.3390/polym15132785.
3
In situ tribochemical sulfurization of molybdenum oxide nanotubes.原位摩擦化学硫化氧化钼纳米管。
Nanoscale. 2018 Feb 15;10(7):3281-3290. doi: 10.1039/c7nr05830f.
4
Influence of the Synergistic Effect of Multi-Walled Carbon Nanotubes and Carbon Fibers in the Rubber Matrix on the Friction and Wear of Metals during the Mixing Process.多壁碳纳米管与碳纤维在橡胶基体中的协同效应在混合过程中对金属摩擦磨损的影响
Polymers (Basel). 2022 Sep 7;14(18):3731. doi: 10.3390/polym14183731.
5
Interfacial antiwear and physicochemical properties of alkylborate-dithiophosphates.烷基硼酸酯-二硫代磷酸酯的界面抗磨及物理化学性能。
ACS Appl Mater Interfaces. 2011 Apr;3(4):956-68. doi: 10.1021/am101203t. Epub 2011 Mar 22.
6
Tribochemical Interactions between Carbon Nanotubes and ZDDP Antiwear Additive during Tribofilm Formation on Uncoated and DLC-Coated Steel.在未涂层和类金刚石碳涂层钢表面形成摩擦膜的过程中，碳纳米管与ZDDP抗磨添加剂之间的摩擦化学相互作用
Materials (Basel). 2020 May 23;13(10):2409. doi: 10.3390/ma13102409.
7
Tribological Performance of Nanocomposite Carbon Lubricant Additive.纳米复合碳润滑添加剂的摩擦学性能
Materials (Basel). 2019 Jan 4;12(1):149. doi: 10.3390/ma12010149.
8
Carbon-Based Functional Nanomaterials as Tools for Controlling the Kinetics of Tribochemical Reactions.基于碳的功能纳米材料作为控制摩擦化学反应动力学的工具。
Materials (Basel). 2024 Feb 6;17(4):785. doi: 10.3390/ma17040785.
9
Effect of MWCNTs on Wear Behavior of Epoxy Resin for Aircraft Applications.多壁碳纳米管对航空用环氧树脂磨损行为的影响
Materials (Basel). 2020 Jun 12;13(12):2696. doi: 10.3390/ma13122696.
10
Behavior of Wear Debris and Its Action Mechanism on the Tribological Properties of Medium-Carbon Steel with Magnetic Field.磨损碎屑行为及其对磁场作用下中碳钢摩擦学性能的作用机制
Materials (Basel). 2018 Dec 24;12(1):45. doi: 10.3390/ma12010045.

引用本文的文献

1
Tribological Properties of Cu-MoS-WS-Ag-CNT Sintered Composite Materials.铜-二硫化钼-二硫化钨-银-碳纳米管烧结复合材料的摩擦学性能
Materials (Basel). 2022 Nov 26;15(23):8424. doi: 10.3390/ma15238424.
2
Machine Learning Approach for Application-Tailored Nanolubricants' Design.用于定制应用的纳米润滑剂设计的机器学习方法
Nanomaterials (Basel). 2022 May 22;12(10):1765. doi: 10.3390/nano12101765.
3
A Review of Friction Performance of Lubricants with Nano Additives.含纳米添加剂润滑剂的摩擦性能综述

本文引用的文献

1
Graphene-Ionic Liquid Thin Film Nanolubricant.石墨烯-离子液体薄膜纳米润滑剂
Nanomaterials (Basel). 2020 Mar 17;10(3):535. doi: 10.3390/nano10030535.
2
Carbon-based tribofilms from lubricating oils.含碳摩擦膜的润滑油。
Nature. 2016 Aug 4;536(7614):67-71. doi: 10.1038/nature18948.
3
Supercritical Fluid Synthesis and Tribological Applications of Silver Nanoparticle-decorated Graphene in Engine Oil Nanofluid.超临界流体合成及银纳米颗粒修饰石墨烯在发动机油纳米流体中的摩擦学应用
Materials (Basel). 2021 Oct 22;14(21):6310. doi: 10.3390/ma14216310.
Sci Rep. 2016 Aug 4;6:31246. doi: 10.1038/srep31246.
4
Tribology. Mechanisms of antiwear tribofilm growth revealed in situ by single-asperity sliding contacts.摩擦学。通过单峰滑动接触原位揭示抗磨摩擦膜生长的机制。
Science. 2015 Apr 3;348(6230):102-6. doi: 10.1126/science.1258788. Epub 2015 Mar 12.
5
Carbon nanotubes: present and future commercial applications.碳纳米管：当前和未来的商业应用。
Science. 2013 Feb 1;339(6119):535-9. doi: 10.1126/science.1222453.
6
Graphene-based engine oil nanofluids for tribological applications.基于石墨烯的发动机油纳米流体在摩擦学中的应用。
ACS Appl Mater Interfaces. 2011 Nov;3(11):4221-7. doi: 10.1021/am200851z. Epub 2011 Oct 21.
7
Multiwall carbon nanotubes: synthesis and application.多壁碳纳米管：合成与应用
Acc Chem Res. 2002 Dec;35(12):1008-17. doi: 10.1021/ar010151m.
8
Carbon nanotubes--the route toward applications.碳纳米管——通往应用之路。
Science. 2002 Aug 2;297(5582):787-92. doi: 10.1126/science.1060928.