配体促进的金催化烯烃的1,2-杂芳基化反应。
Ligand-enabled gold-catalyzed 1,2-heteroarylation of alkenes.
作者信息
Tathe Akash G, Chintawar Chetan C, Bhoyare Vivek W, Patil Nitin T
机构信息
Department of Chemistry, Indian Institute of Science Education and Research (IISER), Bhopal Bypass Road, Bhauri, Bhopal - 462 066, India.
出版信息
Chem Commun (Camb). 2020 Aug 21;56(65):9304-9307. doi: 10.1039/d0cc03707a. Epub 2020 Jul 15.
By adopting the interplay between ligand-enabled Au(i)/Au(iii) catalysis and the unique π-activation mode of gold complexes, a highly coveted 1,2-heteroarylation of alkenes has been accomplished. The present ligand-enabled approach not only circumvents the requirement for strong sacrificial oxidants or photocatalysts but also operates under mild reaction conditions by utilizing simple and non-prefunctionalized aryl coupling partners.
通过采用配体促进的Au(i)/Au(iii)催化与金配合物独特的π活化模式之间的相互作用，实现了备受期待的烯烃1,2-杂芳基化反应。目前这种配体促进的方法不仅避免了对强牺牲性氧化剂或光催化剂的需求，而且通过使用简单且未预官能化的芳基偶联试剂，在温和的反应条件下即可进行反应。
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