Department of Environment, Faculty of Natural Resources, Yazd University, Yazd, Iran.
Department of Environment, Faculty of Natural Resources, University of Tehran, Karaj, Iran.
Sci Total Environ. 2020 Nov 20;744:140762. doi: 10.1016/j.scitotenv.2020.140762. Epub 2020 Jul 12.
The levels of Cd, Cr, Cu, Fe, Mn, Pb and Zn were determined in floor dusts from mechanical (MRWs) and battery repairing workshops (BRWs) in Yazd, Iran. The study aimed to evaluate the anthropogenic contribution to the presence of heavy metals (HMs), the possible sources and the related risks that could arise from occupational exposure in the studied workplace microenvironments. Among the analyzed heavy metals, Cu, Pb and Zn exhibited enhanced concentrations in the floor dusts. The EF calculations showed an extremely severe enrichment of HMs, especially for Cd, Cu and Pb, while floor dusts were characterized as "extremely polluted" with regards to those metals. In any case, both EF and I values were significantly higher in the BRWs. These results were also supported by NIPI and PLI values, while contour maps of PLI values in both MRWs and BRWs outlined workshops in N-NE part of Yazd as more impacted compared to other spatial locations. Principal component analysis (PCA) and Pearson's correlation outscored workshops activities as the principal sources of heavy metals. The health risk assessment suggested considerable non-carcinogenic risks regarding Pb in the BRWs which exhibited HQ (mean 2.91) and HI (mean 3.03) values higher than safe level. Regarding carcinogenic risks, CR values for both Cd and Cr were below the safe level (1.0 × 10). The occupational exposure to Pb was evaluated through the predicted BLL values, where with averages of 3.33 μg/dl and 21.4 μg/dl for MRWs and BRWs workers, respectively, indicated a severe Pb exposure for BRWs workers.
在伊朗亚兹德的机械(MRWs)和电池修理车间(BRWs)中,测定了地板灰尘中的 Cd、Cr、Cu、Fe、Mn、Pb 和 Zn 水平。该研究旨在评估人为因素对重金属(HMs)存在的贡献、可能的来源以及在研究工作场所微环境中可能因职业暴露而产生的相关风险。在所分析的重金属中,Cu、Pb 和 Zn 在地板灰尘中的浓度增加。EF 计算表明,重金属的富集程度非常严重,特别是 Cd、Cu 和 Pb,而地板灰尘则被认为是这些金属的“极度污染”。在任何情况下,EF 和 I 值在 BRWs 中都显著更高。NIPI 和 PLI 值也支持了这些结果,而在 MRWs 和 BRWs 中,PLI 值的等高线图概述了 Yazd 的 N-NE 部分的车间比其他空间位置受到更大的影响。主成分分析(PCA)和 Pearson 相关系数表明,车间活动是重金属的主要来源。健康风险评估表明,BRWs 中 Pb 存在相当大的非致癌风险,其 HQ(平均值 2.91)和 HI(平均值 3.03)值高于安全水平。关于致癌风险,Cd 和 Cr 的 CR 值均低于安全水平(1.0×10)。通过预测 BLL 值评估职业性 Pb 暴露,MRWs 和 BRWs 工人的平均值分别为 3.33μg/dl 和 21.4μg/dl,表明 BRWs 工人的 Pb 暴露严重。