Minisy Islam M, Bober Patrycja
Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic.
Faculty of Science, Charles University, 128 43, Prague 2, Czech Republic.
Macromol Rapid Commun. 2020 Sep;41(17):e2000364. doi: 10.1002/marc.202000364. Epub 2020 Aug 9.
Polypyrrole (PPy) is oxidatively polymerized in the frozen state at -24 °C in the presence of various organic dyes as morphology guiding agents in order to form homogeneous 1D PPy nanoforms. The freezing polymerization of pyrrole has a significant influence on the electrical conductivity and thermal stability but negligible influence on the yield compared to widely used room temperature polymerization.
聚吡咯(PPy)在-24℃的冷冻状态下,在各种有机染料作为形貌导向剂的存在下进行氧化聚合,以形成均匀的一维PPy纳米形态。与广泛使用的室温聚合相比,吡咯的冷冻聚合对电导率和热稳定性有显著影响,但对产率的影响可忽略不计。