Ag-Modified g-CN Prepared by a One-Step Calcination Method for Enhanced Catalytic Efficiency and Stability.

Ag-decorated g-CN (denoted as Ag/CN-) was prepared by a one-step calcination method, and the influences of calcination time on structure, morphology, surface composition, photocatalytic performance, and catalytic reduction activity of the prepared Ag/CN- samples were investigated. The tests showed that the Ag/CN-8 prepared through by calcination for 8 h exhibited the best photocatalytic degradation efficiency of methyl orange (98.7% within 2 h) and the best catalytic reduction property of 4-nitrophenol (100% within 70 s). Meanwhile, these Ag/CN- samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectra (DRS), photoluminescence (PL), photocurrent response, and electrochemical impedance spectroscopy (EIS) Nyquist plots. It was found that the Ag/CN-8 prepared through calcination for 8 h had a higher specific surface area, higher dispersibility of silver nanoparticles (Ag NPs), the widest range of visible light response, and the lowest photogenerated electron-hole recombination rate. The results of the trapping experiments indicated that a superoxide radical plays a major role. Moreover, a possible mechanism of photocatalytic degradation in methyl orange and catalytic reduction 4-nitrophenol was proposed.