Hunan Provincial Key Laboratory of Cytochemistry, College of Chemistry and Food Engineering, Changsha University of Science & Technology, Changsha 410114, China.
Int J Mol Sci. 2020 Aug 14;21(16):5839. doi: 10.3390/ijms21165839.
Porphyrins have planar and conjugated structures, good optical properties, and other special functional properties. Owing to these excellent properties, in recent years, porphyrins and their analogues have emerged as a multifunctional platform for chemical sensors. The rich chemistry of these molecules offers many possibilities for metal ions detection. This review mainly discusses two types of molecular porphyrin and porphyrin composite sensors for metal ions detection, because porphyrins can be functionalized to improve their functional properties, which can introduce more chemical and functional sites. According to the different application materials, the section of porphyrin composite sensors is divided into five sub-categories: (1) porphyrin film, (2) porphyrin metal complex, (3) metal-organic frameworks, (4) graphene materials, and (5) other materials, respectively.
卟啉具有平面和共轭结构、良好的光学性质和其他特殊功能性质。由于这些优异的性质,近年来,卟啉及其类似物已成为化学传感器的多功能平台。这些分子丰富的化学性质为金属离子检测提供了多种可能性。本综述主要讨论了两种类型的分子卟啉和卟啉复合传感器用于金属离子检测,因为卟啉可以进行功能化以改善其功能性质,从而可以引入更多的化学和功能位点。根据不同的应用材料,将卟啉复合传感器的部分分为五个子类:(1)卟啉膜,(2)卟啉金属配合物,(3)金属有机骨架,(4)石墨烯材料和(5)其他材料。