Ghallab Rochdi, Boutebdja Mehdi, Dénès George, Merazig Hocine
Environmental Molecular, and Structural Chemistry Research Unit, University of, Constantine-1, 25000, Constantine, Algeria.
Laboratory of Solid State Chemistry and Mossbauer Spectroscopy, Departement of, Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St. West, Montreal, H4B 1R6, QC, Canada.
Acta Crystallogr E Crystallogr Commun. 2020 Jul 17;76(Pt 8):1279-1283. doi: 10.1107/S205698902000941X. eCollection 2020 Aug 1.
In the title mol-ecular salt, (CHN)[SnCl], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H⋯Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.
在标题分子盐(CHN)[SnCl]中，阳离子在吡啶N原子处质子化，完整的二价阴离子由一个晶体学对称中心产生。在晶体中，N-H⋯Cl氢键将各组分连接成一个三维网络，该网络由交替的阳离子层和阴离子层堆叠而成。已根据阳离子和阴离子的 Hirshfeld 表面分析了分子间相互作用的性质。报道了标题化合物的热行为和拉曼光谱。
