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双(2-氨基吡啶鎓)六氯锡(IV)酸盐的合成、晶体结构及 Hirshfeld 表面

Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).

作者信息

Ghallab Rochdi, Boutebdja Mehdi, Dénès George, Merazig Hocine

机构信息

Environmental Molecular, and Structural Chemistry Research Unit, University of, Constantine-1, 25000, Constantine, Algeria.

Laboratory of Solid State Chemistry and Mossbauer Spectroscopy, Departement of, Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St. West, Montreal, H4B 1R6, QC, Canada.

出版信息

Acta Crystallogr E Crystallogr Commun. 2020 Jul 17;76(Pt 8):1279-1283. doi: 10.1107/S205698902000941X. eCollection 2020 Aug 1.

Abstract

In the title mol-ecular salt, (CHN)[SnCl], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H⋯Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.

摘要

在标题分子盐(CHN)[SnCl]中,阳离子在吡啶N原子处质子化,完整的二价阴离子由一个晶体学对称中心产生。在晶体中,N-H⋯Cl氢键将各组分连接成一个三维网络,该网络由交替的阳离子层和阴离子层堆叠而成。已根据阳离子和阴离子的 Hirshfeld 表面分析了分子间相互作用的性质。报道了标题化合物的热行为和拉曼光谱。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/963f/7405591/13db469764c7/e-76-01279-fig1.jpg

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