Ghallab Rochdi, Bougueria Hassiba, Merazig Hocine
Environmental Molecular and Structural Chemistry Research Unit, University of Constantine-1, 25000, Constantine, Algeria.
IUCrdata. 2022 Mar 3;7(Pt 3):x220191. doi: 10.1107/S2414314622001912. eCollection 2022 Mar.
The title hybrid compound, (CHNCl)[SnCl]·2HO, was synthesized and its structure was identified by single-crystal X-ray diffraction. The structure is non-polymeric (0D) in terms of containing isolated [SnCl] polyhedra. The special position (0,0,0) of the Sn atom in the crystal structure gives rise to a stacking structure with alternating cationic and anionic layers parallel to (001). The water mol-ecules are inter-calated between these layers, which are linked by cation-anion hydrogen bonds and dominant non-covalent inter-actions. The stability of the three-dimensional network for this compound is also discussed.
标题杂化化合物(CHNCl)[SnCl]·2HO被合成出来，并通过单晶X射线衍射确定了其结构。就包含孤立的[SnCl]多面体而言，该结构是非聚合的(零维)。晶体结构中Sn原子的特殊位置(0,0,0)产生了一种具有平行于(001)的交替阳离子层和阴离子层的堆积结构。水分子插层在这些层之间，这些层通过阳离子-阴离子氢键和主要的非共价相互作用相连。还讨论了该化合物三维网络的稳定性。
