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二水合六氯锡（IV）酸双（2-羧基喹啉鎓）盐

Bis(2-carb-oxy-quinolinium) hexa-chlorido-stan-nate(IV) dihydrate.

作者信息

Benhamada Mohamed Siradj Eddine, Benlatreche Tarek, Ghallab Rochdi, Dénès George, Merazig Hocine

机构信息

Environmental Molecular and Structural Chemistry Research Unit University of Constantine-1 25000 Constantine Algeria.

Ecole Nationale Polytechnique de Constantine (ENPC) Laboratoire de Technologie des Matériaux Avancés Algeria.

出版信息

IUCrdata. 2024 Aug 30;9(Pt 8):x240826. doi: 10.1107/S2414314624008265. eCollection 2024 Aug.

DOI:10.1107/S2414314624008265
PMID:39247079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11375601/
Abstract

In the hydrated title salt, (CHNO)[SnCl]·2HO, the tin(IV) atom is located about a center of inversion. In the crystal structure, the organic cation, the octa-hedral inorganic anion and the water mol-ecule of crystallization inter-act through O-H⋯O, N-H⋯O and O-H⋯Cl hydrogen bonds, supplemented by weak π-π stacking between neighboring cations, and C-Cl⋯π inter-actions.

摘要

在水合标题盐(CHNO)[SnCl]·2HO中，锡(IV)原子位于一个反演中心附近。在晶体结构中，有机阳离子、八面体无机阴离子和结晶水分子通过O-H⋯O、N-H⋯O和O-H⋯Cl氢键相互作用，并辅以相邻阳离子之间的弱π-π堆积以及C-Cl⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/afc808ef4dc2/x-09-x240826-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/af1fa56e7b5e/x-09-x240826-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/7301ffcdde34/x-09-x240826-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/afc808ef4dc2/x-09-x240826-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/af1fa56e7b5e/x-09-x240826-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/7301ffcdde34/x-09-x240826-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b6b/11375601/afc808ef4dc2/x-09-x240826-fig3.jpg

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本文引用的文献

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