Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene.
作者信息
Xu Qi, Wang Chu, Zhao Yu, Zheng Dan, Shao Chengyuan, Guo Weijie, Deng Xuebin, Wang Ying, Chen Xuebo, Zhu Jun, Jiang Hua
机构信息
College of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.
出版信息
Org Lett. 2020 Sep 18;22(18):7397-7402. doi: 10.1021/acs.orglett.0c02754. Epub 2020 Sep 9.
The selective fusions with pyrene derivative to the rim and flank bonds of corannulene generated and , respectively, which underwent a Scholl reaction to provide novel distorted PAHs and , consisting of corannulene and dibenzocoronene units with different connections between them. The studies revealed that the properties of these PAHs are highly dependent on the fusing positions of corannulene.
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