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二维和三维金属有机框架的超声合成、表征及其在氧化酰胺化反应中的应用

Ultrasonic Synthesis and Characterization of 2D and 3D Metal-Organic Frameworks and Their Application in the Oxidative Amidation Reaction.

作者信息

Bagheri Sepideh, Pazoki Farzane, Heydari Akbar

机构信息

Department of Chemical, Faculty of Sciences, Tarbiat Modares University, Tehran 14115-4838, Iran.

出版信息

ACS Omega. 2020 Aug 21;5(34):21412-21419. doi: 10.1021/acsomega.0c01773. eCollection 2020 Sep 1.

DOI:10.1021/acsomega.0c01773
PMID:32905222
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7469125/
Abstract

Ultrasound irradiation as an environmentally friendly and inexpensive method successfully applied for the synthesis of two-dimensional (2D) and three-dimensional (3D) metal-organic frameworks (MOFs). Sonochemically synthesized AM-Co1 and AM-Co2 powder has been employed as a green heterogeneous catalyst for the oxidative amidation reaction. The results show that AM-Co1 with a two-dimensional (2D) structure can act as an excellent catalyst for this reaction under ultrasonic irradiation compared to AM-Co2 with a three-dimensional (3D) structure. According to green principles, we used water as a green solvent and air as an oxidant for the oxidative amidation reaction. A wide variety of aldehydes and amines have been used for the synthesis of amides in good to excellent yields (75-90%). Also, the MOF catalyst could be recovered and reused several times without loss of activity.

摘要

超声辐照作为一种环境友好且成本低廉的方法，已成功应用于二维（2D）和三维（3D）金属有机框架（MOF）的合成。通过声化学合成的AM-Co1和AM-Co2粉末已被用作氧化酰胺化反应的绿色多相催化剂。结果表明，与具有三维（3D）结构的AM-Co2相比，具有二维（2D）结构的AM-Co1在超声辐照下可作为该反应的优良催化剂。根据绿色化学原则，我们使用水作为绿色溶剂，空气作为氧化酰胺化反应的氧化剂。多种醛和胺已被用于合成酰胺，产率良好至优异（75-90%）。此外，MOF催化剂可以回收并重复使用多次而不失活。

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