Nanoporous Composites of CoO Quantum Dots and ZIF-Derived Carbon as High-Performance Anodes for Lithium-Ion Batteries.

Transition-metal oxides are attracting considerable attention as anodes for lithium-ion batteries because of their high reversible capacities. However, the drastic volume change and inferior electrical conductivity greatly retard their widespread applications in lithium-ion batteries. Herein, three-dimensional nanoporous composites of CoO (CoO and CoO) quantum dots and zeolitic imidazolate framework-67-derived carbon are fabricated by a precipitation method. The carbon prepared by carbonization of zeolitic imidazolate framework-67 can greatly enhance the electrical conductivity of the composite anodes. CoO quantum dots anchored firmly on zeolitic imidazolate framework-67-derived carbon can effectively inhibit the aggregation and volume change of CoO quantum dots during lithiation/delithiation processes. The nanoporous structure can shorten the ion diffusion paths and maintain the structural integrity upon cycling. Meanwhile, kinetics analysis reveals that a capacitance mechanism dominates the lithium storage capacity, which can greatly enhance the electrochemical performance. The composite anodes show a high discharge capacity of 1873 mAh g after 200 cycles at 200 mA g, ultralong cycle life (1246 mAh g after 900 cycles at 1000 mA g), and improved rate performance. This work may provide guidelines for preparing cobalt oxide-based anodes for LIBs.