Self-healing materials: a review.

The ability of materials to self-heal from mechanical and thermally induced damage is explored in this paper and has significance in the field of fracture and fatigue. The history and evolution of several self-repair systems is examined including nano-beam healing elements, passive self-healing, autonomic self-healing and ballistic self-repair. Self-healing mechanisms utilized in the design of these unusual materials draw much information from the related field of polymer-polymer interfaces and crack healing. The relationship of material damage to material healing is examined in a manner to provide an understanding of the kinetics and damage reversal processes necessary to impart self-healing characteristics. In self-healing systems, there are transitions from hard-to-soft matter in ballistic impact and solvent bonding and conversely, soft-to-hard matter transitions in high rate yielding materials and shear-thickening fluids. These transitions are examined in terms of a new theory of the glass transition and yielding, viz., the twinkling fractal theory of the hard-to-soft matter transition. Success in the design of self-healing materials has important consequences for material safety, product performance and enhanced fatigue lifetime.