Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chemistry, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou 570228, China.
J Org Chem. 2020 Nov 20;85(22):14653-14663. doi: 10.1021/acs.joc.0c01557. Epub 2020 Sep 21.
The controllable phosphorylations of thioesters were developed. When the reaction was catalyzed by a palladium catalyst, aryl or alkenyl phosphoryl compounds were generated through decarbonylative coupling, while the benzyl phosphoryl compounds were produced through deoxygenative coupling when the reaction was carried out in the presence of only a base.
发展了硫酯的可控磷酸化反应。当反应由钯催化剂催化时，通过脱羰基偶联生成芳基或烯基磷酸酯化合物，而当仅在碱存在下进行反应时，则通过脱氧偶联生成苄基磷酸酯化合物。
