一种基于三氟甲磺酸亚钠介导的光催化策略，用于醇的有氧氧化。
A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for aerobic oxidation of alcohols.
机构信息
Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
出版信息
Chem Commun (Camb). 2020 Oct 15;56(82):12443-12446. doi: 10.1039/d0cc05799a.
PMID:32940293
Abstract
A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for the aerobic oxidation of alcohols has been developed for the first time, and the photoredox aerobic oxidation of secondary and primary alcohols provided the corresponding ketones and carboxylic acids, respectively, in high to excellent yields.
摘要
首次开发了一种三氟甲磺酸亚钠介导的光催化策略，用于醇的有氧氧化，并且光氧化有氧氧化仲醇和伯醇分别提供了相应的酮和羧酸，产率高至优异。
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