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污泥生物炭的制备、性质及其在环境修复中的催化应用。

Production, properties, and catalytic applications of sludge derived biochar for environmental remediation.

机构信息

School of Civil and Environmental Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, Guangdong 518055, China; State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China.

State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China.

出版信息

Water Res. 2020 Dec 15;187:116390. doi: 10.1016/j.watres.2020.116390. Epub 2020 Sep 5.

Abstract

Environment-friendly and cost-effective disposal and reutilization of sludge wastes are essential in wastewater treatment processes (WWTPs). Converting activated sludge into biochar via thermochemical treatment is a promising technology for waste management in WWTPs. This review summarizes the compositions of sludge, the dewatering methods, and the thermochemical methods whichinfluence the structures, chemistry, and catalytic performances of the derived biochar. Moreover, the physiochemical characteristics and chemical stability of sludge biochar are discussed. Catalytic applications of biochar are highlighted, including the reaction mechanisms and feasibility for catalytic removal of organic contaminants. High-temperature carbonized sludge biochar exhibits excellent performance for persulfate activation in advanced oxidation processes due to the graphitic carbon structure, newly-created active sites, and fine-tuned metal species. Therefore, the sludge biochar can be produced via cost-effective and eco-friendly approaches to immobilize harmful components from sludge and remediate organic pollution in wastewater, offering a sustainable route toward sludge reutilization into value-added products for water purification.

摘要

在污水处理厂(WWTP)中,实现污泥废物的环保且具成本效益的处理和再利用至关重要。通过热化学处理将活性污泥转化为生物炭是 WWTP 中废物管理的一项很有前途的技术。本综述总结了污泥的组成、脱水方法以及热化学方法,这些因素影响了所得生物炭的结构、化学性质和催化性能。此外,还讨论了污泥生物炭的物理化学特性和化学稳定性。生物炭的催化应用也得到了强调,包括反应机制和催化去除有机污染物的可行性。由于具有石墨碳结构、新生成的活性位点和精细调节的金属物种,高温碳化的污泥生物炭在高级氧化过程中对过硫酸盐的活化表现出优异的性能。因此,可以通过经济高效且环保的方法生产污泥生物炭,以固定污泥中的有害成分并修复废水中的有机污染,为将污泥再利用为用于水净化的增值产品提供了可持续的途径。

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