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非晶态材料因机械自组织而产生的突发固态化。

Emergent solidity of amorphous materials as a consequence of mechanical self-organisation.

作者信息

Tong Hua, Sengupta Shiladitya, Tanaka Hajime

机构信息

School of Physics and Astronomy, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240, China.

Department of Fundamental Engineering, Institute of Industrial Science, University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan.

出版信息

Nat Commun. 2020 Sep 25;11(1):4863. doi: 10.1038/s41467-020-18663-7.

Abstract

Amorphous solids have peculiar properties distinct from crystals. One of the most fundamental mysteries is the emergence of solidity in such nonequilibrium, disordered state without the protection by long-range translational order. A jammed system at zero temperature, although marginally stable, has solidity stemming from the space-spanning force network, which gives rise to the long-range stress correlation. Here, we show that such nonlocal correlation already appears at the nonequilibrium glass transition upon cooling. This is surprising since we also find that the system suffers from giant anharmonic fluctuations originated from the fractal-like potential energy landscape. We reveal that it is the percolation of the force-bearing network that allows long-range stress transmission even under such circumstance. Thus, the emergent solidity of amorphous materials is a consequence of nontrivial self-organisation of the disordered mechanical architecture. Our findings point to the significance of understanding amorphous solids and nonequilibrium glass transition from a mechanical perspective.

摘要

非晶态固体具有与晶体不同的独特性质。最基本的谜团之一是,在这种非平衡、无序状态下,没有长程平移有序的保护,固体性是如何出现的。零温度下的堵塞系统虽然处于边缘稳定状态,但其固体性源于跨越空间的力网络,这导致了长程应力相关性。在这里,我们表明,这种非局部相关性在冷却时的非平衡玻璃化转变中就已经出现。这很令人惊讶,因为我们还发现该系统存在源于分形似的势能景观的巨大非谐涨落。我们揭示,即使在这种情况下,承载力网络的渗流也允许长程应力传递。因此,非晶态材料中出现的固体性是无序机械结构非平凡自组织的结果。我们的发现指出了从力学角度理解非晶态固体和非平衡玻璃化转变的重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32fa/7519136/eaaa0c225c59/41467_2020_18663_Fig1_HTML.jpg

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