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检测从 L. 和 L. 的树皮提取物中的黄酮 C-糖苷。

Detection of flavone C-glycosides in the extracts from the bark of L. and L.

机构信息

Department of Food Biochemistry and Analysis, Poznań University of Life Sciences, Poznań, Poland.

Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland.

出版信息

Eur J Mass Spectrom (Chichester). 2020 Oct;26(5):369-375. doi: 10.1177/1469066720963003. Epub 2020 Sep 30.

DOI:10.1177/1469066720963003
PMID:32996331
Abstract

The extracts from the bark of and have been analyzed by using high pressure liquid chromatography/electrospray ionization mass spectrometry. For the first time in the bark of species flavonoid C-glycosides have been detected. On the basis of the characteristic fragmentation patterns of their [M-H] and [M + H] ions, three flavonoid C-glycosides have been identified, namely apigenin-6,8-di-C-glucoside (vicenin-2), apigenin-6-C-glucoside (isovitexin) and chrysin-8-C-glucoside. Taking into account the widely studied biological activities of flavonoid C-glycosides, the barks of these common fruit trees seem to be interesting materials of potential medical or cosmetic application.

摘要

采用高效液相色谱/电喷雾电离质谱法分析了 和 的树皮提取物。首次在 种的树皮中检测到类黄酮 C-糖苷。根据其 [M-H] 和 [M+H] 离子的特征裂解模式,鉴定出三种类黄酮 C-糖苷,即芹菜素-6,8-二-C-葡萄糖苷(vicenin-2)、芹菜素-6-C-葡萄糖苷(异荭草苷)和白杨素-8-C-葡萄糖苷。考虑到类黄酮 C-糖苷广泛研究的生物活性,这些常见果树的树皮似乎是具有潜在医学或化妆品应用的有趣材料。

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