一种从金属有机笼组装超分子配位聚合物的共价去保护策略。
A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages.
机构信息
Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia.
出版信息
Chem Commun (Camb). 2020 Nov 4;56(85):12969-12972. doi: 10.1039/d0cc05349j. Epub 2020 Sep 30.
PMID:32996491
Abstract
A CuL metal-organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline-copper coordination and possess a tunable porosity based on the rate of deprotection.
摘要
一种由胺保护配体制成的 CuL 金属有机笼（MOC），在共价后组装脱保护后形成超分子配位聚合物（SCP）。无定形的 SCPs 是通过苯胺-铜配位形成的，并且根据脱保护的速率具有可调节的孔隙率。
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