TFA 催化的环丁醇的[3+2]螺环化反应：构建螺[环丁[a]茚-7,1'-环丁烷]骨架的方法。
TFA-Catalyzed [3+2] Spiroannulation of Cyclobutanols: A Route to Spiro[cyclobuta[a]indene-7,1'-cyclobutane] Skeletons.
机构信息
State Key Laboratory of Applied Organic Chemistry, Key laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, P. R. China.
Chemical Science and Engineering College, North Minzu University, Yinchuan, 750000, P. R. China.
出版信息
Chem Asian J. 2020 Nov 16;15(22):3812-3815. doi: 10.1002/asia.202001048. Epub 2020 Oct 14.
A straightforward method for the synthesis of spiro[cyclobuta[a]indene-7,1'-cyclobutane] derivatives from cyclobutanols has been developed via one-pot [3+2] spiroannulation. A series of new spiro[cyclobuta[a]indene-7,1'-cyclobutane] derivatives are facilely synthesized in good yields under mild reaction conditions.
已经开发出一种从环丁醇一锅法[3+2]螺环化合成螺[环丁[a]茚-7,1'-环丁烷]衍生物的简便方法。在温和的反应条件下，一系列新的螺[环丁[a]茚-7,1'-环丁烷]衍生物以良好的收率容易地合成。
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