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具有结晶骨架的绣球状介孔 WO 纳米花用于 3-羟基-2-丁酮传感。

Hydrangea-like mesoporous WO nanoflowers with crystalline framework for 3-hydroxy-2-butanone sensing.

机构信息

School of Medical Instrument and Food Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, China.

出版信息

Anal Bioanal Chem. 2020 Dec;412(30):8371-8378. doi: 10.1007/s00216-020-02973-2. Epub 2020 Oct 3.

Abstract

In this study, a simple and efficient strategy for the construction of hydrangea-like mesoporous WO nanoflowers templated using diblock copolymer PS-PtBA was developed. The nanoflower shows good gas sensing properties, especially for 3-hydroxy-2-butanone (3H-2B), which is the signature metabolite of Listeria monocytogenes (L. monocytogenes). Therefore, the gas sensing of 3H-2B by hydrangea-like mesoporous WO nanoflowers can be used to detect L. monocytogenes. In the case of 25 ppm 3H-2B as target gas, the response (R/R) of the hydrangea-like mesoporous WO nanoflowers at 205 °C is 152, where R and R are the resistances of the sensing device in air and target gas, respectively, and the response and recovery times at 25 ppm are 25 s and 146 s, respectively. Schematic illustration of the formation of hydrangea-like mesoporous WO nanoflowers and its gas sensing implication.

摘要

在这项研究中,开发了一种使用两亲嵌段共聚物 PS-PtBA 模板制备绣球花状介孔 WO 纳米花的简单高效策略。纳米花表现出良好的气体传感性能,特别是对 3-羟基-2-丁酮(3H-2B),3H-2B 是李斯特菌(Listeria monocytogenes,L. monocytogenes)的特征代谢物。因此,绣球花状介孔 WO 纳米花对 3H-2B 的气敏可以用于检测李斯特菌。在以 25 ppm 3H-2B 为目标气体的情况下,在 205°C 时,绣球花状介孔 WO 纳米花的响应(R/R)为 152,其中 R 和 R 分别为传感器在空气中和目标气体中的电阻,在 25 ppm 时的响应和恢复时间分别为 25 s 和 146 s。绣球花状介孔 WO 纳米花的形成及其气体传感意义示意图。

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