College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, China.
State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
Biosensors (Basel). 2022 Sep 28;12(10):803. doi: 10.3390/bios12100803.
is a hazardous foodborne pathogen that is able to cause acute meningitis, encephalitis, and sepsis to humans. The efficient detection of 3-hydroxy-2-butanone, which has been verified as a biomarker for the exhalation of , can feasibly evaluate whether the bacteria are contained in food. Herein, we developed an outstanding 3-hydroxy-2-butanone gas sensor based on the microelectromechanical systems using Au/ZnO NS as a sensing material. In this work, ZnO nanosheets were synthesized by a hydrothermal reaction, and Au nanoparticles (~5.5 nm) were prepared via an oleylamine reduction method. Then, an ultrasonic treatment was carried out to modified Au nanoparticles onto ZnO nanosheets. The XRD, BET, TEM, and XPS were used to characterize their morphology, microstructure, catalytic structure, specific surface area, and chemical composition. The response of the 1.0% Au/ZnO NS sensors vs. 25 ppm 3-hydroxy-2-butanone was up to 174.04 at 230 °C. Moreover, these sensors presented fast response/recovery time (6 s/7 s), great selectivity, and an outstanding limit of detection (lower than 0.5 ppm). This work is full of promise for developing a nondestructive, rapid and practical sensor, which would improve evaluation in foods.
是一种食源性危险致病菌,能够导致人类急性脑膜炎、脑炎和败血症。能够呼出的 3-羟基-2-丁酮的有效检测,可切实评估食品中是否含有该细菌。在此,我们采用微电子机械系统(microelectromechanical systems),利用 Au/ZnO NS 作为传感材料,开发了一种出色的 3-羟基-2-丁酮气体传感器。在这项工作中,通过水热反应合成了 ZnO 纳米片,并通过油胺还原法制备了约 5.5nm 的 Au 纳米颗粒。然后,通过超声处理将 Au 纳米颗粒修饰到 ZnO 纳米片上。采用 XRD、BET、TEM 和 XPS 对其形貌、微观结构、催化结构、比表面积和化学组成进行了表征。在 230°C 时,1.0% Au/ZnO NS 传感器对 25ppm 3-羟基-2-丁酮的响应值高达 174.04。此外,这些传感器具有快速的响应/恢复时间(6s/7s)、出色的选择性和优异的检测限(低于 0.5ppm)。这项工作为开发无损、快速和实用的传感器充满了希望,这将改善食品中的评估。