State Key Lab of Metastable Materials Science and Technology, and Collage of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004, China.
Molecules. 2020 Oct 4;25(19):4547. doi: 10.3390/molecules25194547.
Ionic liquids (ILs) are a class of pure ions with melting points lower than 100 °C. They are getting more and more attention because of their high thermal stability, high ionic conductivity and dielectric properties. The unique dielectric properties aroused by the ion motion of ILs makes ILs-contained inorganics or organics responsive to electric field and have great application potential in smart electrorheological (ER) fluids which can be used as the electro-mechanical interface in engineering devices. In this review, we summarized the recent work of various kinds of ILs-contained inorganic ionogels and poly(ionic liquid)s (PILs) as ER materials including their synthesis methods, ER responses and dielectric analysis. The aim of this work is to highlight the advantage of ILs in the synthesis of dielectric materials and their effects in improving ER responses of the materials in a wide temperature range. It is expected to provide valuable suggestions for the development of ILs-contained inorganics and PILs as electric field responsive materials.
离子液体(ILs)是一类熔点低于 100°C 的纯离子。由于其高热稳定性、高离子电导率和介电性能,它们越来越受到关注。ILs 中离子运动引起的独特介电性能使包含 IL 的无机物或有机物对电场有响应,在智能电流变(ER)流体中有很大的应用潜力,可作为工程设备中的机电接口。在这篇综述中,我们总结了各种含 IL 的无机离子凝胶和聚(离子液体)(PILs)作为 ER 材料的最新工作,包括它们的合成方法、ER 响应和介电分析。这项工作的目的是强调 IL 在介电材料合成中的优势,以及它们在提高材料在宽温度范围内的 ER 响应方面的作用。希望为开发含 IL 的无机物和 PILs 作为电场响应材料提供有价值的建议。