Romani Lidia, Malavasi Lorenzo
Department of Chemistry and INSTM, University of Pavia, Via Taramelli 12, Pavia, Pavia 27100, Italy.
ACS Omega. 2020 Sep 28;5(40):25511-25519. doi: 10.1021/acsomega.0c03829. eCollection 2020 Oct 13.
Solar-driven photocatalysis by metal halide perovskites (MHPs) is emerging as an exciting and promising field to promote several relevant catalytic reactions taking advantage of the superior optical properties of MHPs. Their electronic structure is suitable to run reduction reactions (H generation, CO reduction) and even oxidation reactions, in particualr for perovskites with higher band gap values, and further extends their possible use in the field of photochemical organic syntheses. This Mini-Review focuses on the application of MHPs in the solar-driven hydrogen generation with particular emphasis on the materials' design and mechanistic features involved in the catalytic reactions.
金属卤化物钙钛矿（MHP）驱动的太阳能光催化作为一个令人兴奋且充满前景的领域正在兴起，该领域利用MHP卓越的光学特性推动多种相关催化反应。它们的电子结构适合进行还原反应（产氢、CO还原），甚至氧化反应，特别是对于具有较高带隙值的钙钛矿而言，这进一步拓展了其在光化学有机合成领域的潜在应用。本综述聚焦于MHP在太阳能驱动产氢中的应用，尤其着重于催化反应所涉及的材料设计和机理特性。
