School of Mechanical Engineering, SASTRA Deemed University, Tanjavur, Tamil Nadu, 613 401, India.
Sci Rep. 2020 Oct 20;10(1):17815. doi: 10.1038/s41598-020-74130-9.
The present study explores the methodology for the synthesis of bio-oil from waste trichosanthes cucumerina seeds by the solvent extraction method. It investigates the yield percentage, concentration of free fatty acids and acid contents in the extracted bio-oil. Effects of size of the crushed seeds, moisture content, extraction time, solvent to seed ratio and extraction temperatures were examined. The non-polar hexane solvent resulted in a higher percentage of oil yield (28.4 ± 0.4%) for the crushed seed size of 0.21 mm, 6% moisture content, 270 min extraction time, 68 °C temperature and 6:1(ml/g) of solvent to seed ratio. The synthesized bio-oil was characterized using Fourier Transform Infra-Red spectrum and Gas Chromatography-Mass Spectroscopy analysis. The properties of the bio-oil and biodiesel were assessed according to the American Society for Testing and Materials and the Association of Official Analytical Chemists standards. The obtained methyl-ester by trans-esterification process results in the fuel properties closer to the conventional fuel. Thus, Trichosanthes cucumerina bio-diesel can be used as a potential substitute.
本研究探索了通过溶剂萃取法从废弃的佛手瓜种子中合成生物油的方法。考察了提取生物油的产率百分比、游离脂肪酸浓度和酸含量。研究了破碎种子的大小、含水量、提取时间、溶剂与种子比和提取温度的影响。非极性己烷溶剂在破碎种子粒径为 0.21mm、含水量为 6%、提取时间为 270min、温度为 68°C、溶剂与种子比为 6:1(ml/g)的条件下,生物油的产率最高(28.4±0.4%)。采用傅里叶变换红外光谱和气相色谱-质谱分析对合成的生物油进行了表征。根据美国测试材料协会和官方分析化学家协会的标准,评估了生物油和生物柴油的性能。通过酯交换反应得到的甲酯使燃料特性更接近传统燃料。因此,佛手瓜生物柴油可以作为一种潜在的替代品。