Synergism of clay with zinc oxide as nanocatalyst for production of biodiesel from marine Ulva lactuca.

In the present work, Ulva lactuca, a marine macroalgae was used for the production of biodiesel. The ultrasound assisted extraction of oil from autoclaved algal biomass was found effective with maximum yield. The maximum oil was extracted at optimal conditions of 5% moisture content of algal biomass, 0.15 mm size of biomass, 6:1 solvent: solid ratio, at 55 °C in 140 min. The n-hexane with co-solvent methyl tertbutyl ether has shown higher oil when compared to other co-solvents. The extracted oil was transesterified into biodiesel using silica doped with zinc oxide as novel heterogeneous nanocatalyst. The maximum biodiesel yield of 97.43% was obtained at optimized conditions of 800 °C calcination temperature, 8% catalyst concentration, 9:1 methanol to oil ratio, 55 °C reaction temperature and 50 min reaction time. The kinetics of the transesterification reaction was also studied. The Ulva lactuca was found as a potential source for biodiesel production.