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回收 PET 瓶中非食品应用中的污染水平及其对食品接触用再生 PET 安全性的影响。

Contamination Levels in Recollected PET Bottles from Non-Food Applications and their Impact on the Safety of Recycled PET for Food Contact.

机构信息

Fraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Straße 35, 85354 Freising, Germany.

出版信息

Molecules. 2020 Oct 28;25(21):4998. doi: 10.3390/molecules25214998.

DOI:10.3390/molecules25214998
PMID:33126687
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7663040/
Abstract

PET beverage bottles have been recycled and safely reprocessed into new food contact packaging applications for over two decades. During recollection of post-consumer PET beverage bottles, PET containers from non-food products are inevitably co-collected and thereby enter the PET recycling feed stream. To explore the impact of this mixing on the safety-in-use of recycled PET (rPET) bottles, we determined the concentrations of post-consumer substances in PET containers used for a range of non-food product applications taken from the market. Based on the chemical nature and amounts of these post-consumer substances, we evaluated their potential carry-over into beverages filled in rPET bottles starting from different fractions of non-food PET in the recollection systems and taking worst-case cleaning efficiencies of super-clean recycling processes into account. On the basis of the Threshold of Toxicological Concern (TTC) concept and Cramer classification tools, we present a risk assessment for potential exposure of the consumer to the identified contaminants as well as unidentified, potentially genotoxic substances in beverages. As a result, a fraction of 5% non-food PET in the recycling feed stream, which is very likely to occur in the usual recollection systems, does not pose any risk to the consumer. Our data show that fractions of up to 20%, which may sporadically be contained in certain, local recollection systems, would also not raise a safety concern.

摘要

PET 饮料瓶已经回收,并经过安全的再加工,用于 20 多年的新食品接触包装应用。在收集消费后的 PET 饮料瓶时,不可避免地会混入来自非食品产品的 PET 容器,从而进入 PET 回收原料流。为了探索这种混合对回收 PET(rPET)瓶使用安全性的影响,我们确定了从市场上采集的各种非食品产品应用的 PET 容器中消费后的物质的浓度。基于这些消费后的物质的化学性质和数量,我们评估了它们在考虑不同非食品 PET 回收比例和超级清洁回收工艺最差清洁效率的情况下,通过 rPET 瓶进入饮料的潜在残留。基于毒理学关注阈值(TTC)概念和 Cramer 分类工具,我们对消费者在饮料中识别出的污染物以及潜在的遗传毒性物质的潜在暴露风险进行了评估。因此,在通常的收集系统中很可能出现的回收原料流中 5%的非食品 PET 部分不会对消费者构成任何风险。我们的数据表明,在某些局部收集系统中偶尔会包含的高达 20%的分数也不会引起安全问题。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eded/7663040/07f2847a45a3/molecules-25-04998-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eded/7663040/07f2847a45a3/molecules-25-04998-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eded/7663040/07f2847a45a3/molecules-25-04998-g001.jpg

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