Bao Wei Wei, Li Rui, Dai Zhi Cheng, Tang Jian, Shi Xin, Geng Jie Ting, Deng Zhi Feng, Hua Jing
National and Local Joint Engineering Laboratory for Slag Comprehensive Utilization and Environmental Technology, School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong, China.
Key Laboratory of Rubber-Plastic of Ministry of Education (QUST), School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China.
Front Chem. 2020 Sep 10;8:679. doi: 10.3389/fchem.2020.00679. eCollection 2020.
Diketopyrrolopyrrole (DPP) and its derivatives have been widely studied in the past few years due to its intrinsic physical and chemical properties, such as strong electron-withdrawing, deep color, high charge carrier mobility, strong aggregation, good thermal-/photo-stability. In the 1970s, DPP was developed and used only in inks, paints, and plastics. Later, DPP containing materials were found to have potential other applications, typically in electronic devices, which attracted the attention of scientists. In this feature article, the synthesis pathway of DPP-based materials and their applications in organic field-effect transistors, photovoltaic devices, sensors, two photo-absorption materials, and others are reviewed, and possible future applications are discussed. The review outlines a theoretical scaffold for the development of conjugated DPP-based materials, which have multiple potential applications.
由于具有强吸电子性、深色、高载流子迁移率、强聚集性、良好的热稳定性和光稳定性等固有物理化学性质,过去几年中,二酮吡咯并吡咯(DPP)及其衍生物得到了广泛研究。20世纪70年代,DPP被开发出来,仅用于油墨、涂料和塑料。后来,发现含DPP的材料有其他潜在应用,特别是在电子器件领域,这引起了科学家们的关注。在这篇专题文章中,综述了基于DPP的材料的合成途径及其在有机场效应晶体管、光伏器件、传感器、两种光吸收材料等方面的应用,并讨论了可能的未来应用。该综述概述了具有多种潜在应用的共轭DPP基材料开发的理论框架。